Hydrogen bonding in the ethanol-water dimer.

Ian A Finneran1, P Brandon Carroll, Marco A Allodi

  • 1Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 E California Blvd., Pasadena, CA 91125, USA. gab@gps.caltech.edu.

Summary

We determined the ground-state structure of the ethanol-water dimer using microwave spectroscopy. The dimer forms a water-donor/ethanol-acceptor complex with ethanol in a gauche conformation, stabilized by hydrogen bonds.

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