Intercrystal self-assembly for the design of high-quality nickel molybdate nanocrystals

Nanowire of nickel molybdate hydrate, being recognized as an emerging supercapacitor material, was synthesized from the intercrystal self-assembly process (commonly referred to as oriented aggregation or attachment). The detailed lattice image of a NiMoO4·0.75H2O nanowire and the intermediate nanostructure before reaching the interplanar binding were successfully captured by means of high-resolution transmission and scanning electron microscopies. NiMoO4·0.75H2O possessed highly crystalline surface and internal nanostructures.