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Adsorption Kinetics in Nanoscale Porous Coordination Polymers
Satish K Nune1, Praveen K Thallapally2, Benard Peter McGrail1
1Energy & Environment Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
ACS Applied Materials & Interfaces
|September 3, 2015
Abstract:
Nanoscale porous coordination polymers were synthesized using simple wet chemical method. The effect of various polymer surfactants on colloidal stability and shape selectivity was investigated. Our results suggest that the nanoparticles exhibited significantly improved adsorption kinetics compared to bulk crystals due to decreased diffusion path lengths and preferred crystal plane interaction.

