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Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles
Ferdinando Costantino1, Riccardo Vivani, Maria Bastianini
1CEMIN - Dipartimento di Chimica, Biologia e Biotecnologie University of Perugia, Via Elce di Sotto, 8, 06123 Perugia, Italy. luigi.vaccaro@unipg.it.
Chemical Communications (Cambridge, England)
|September 19, 2015
Abstract:
Thin nanosheets from a layered zirconium phosphate-carboxyphosphonate is reported here. Small Pd nanoparticles have been supported on these nanosheets by an efficient method. The resulting Pd-catalyst was fully characterized and tested in the Suzuki-Miyaura coupling. The catalytic system proved its efficiency as it was reused for several cycles and showed low Pd leaching.
