Platinum nanoparticles in suspension are as efficient as Karstedt's complex for alkene hydrosilylation
Thomas Galeandro-Diamant1, Marie-Line Zanota2, Reine Sayah3
1Université de Lyon, Institut de Chimie de Lyon, Laboratoire de Génie des Procédés Catalytiques (UMR 5285 CNRS-CPE Lyon), 43 Bd du 11 Novembre 1918, 69616 Villeurbanne, France. vme@lgpc.cpe.fr and Université de Lyon, Institut de Chimie de Lyon, Laboratoire de Chimie, Catalyse, Polymères et Procédés (UMR 5265 CNRS-Université Lyon 1-CPE Lyon), Équipe Chimie Organométallique de Surface, 43 Bd du 11 Novembre 1918, 69616 Villeurbanne, France. thieuleux@cpe.fr.
Abstract:
Colloidal suspensions of monodisperse platinum nanoparticles of 2 nm diameter have been used to catalyze the hydrosilylation of 1-octene with a polymethylhydrosiloxane. The nanoparticles were found to be as efficient as Karstedt's complex, showing that colloid formation from homogeneous species during hydrosilylation reactions is not necessarily a deactivation pathway. These results also reactivated the debate on whether Karstedt's complex was truly homogeneous or colloidal during catalysis.
More Related Videos
Related Concept Videos
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Heterogeneous Catalysis
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
Catalysis


