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High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal

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Stimuli-Responsive Cubosomes Formed from Blue Phase Liquid Crystals.

Emre Bukusoglu¹, Xiaoguang Wang¹, Jose A Martinez-Gonzalez²

¹Department of Chemical and Biological Engineering, University of Wisconsin-Madison, Madison, WI, 53706, USA.

Advanced Materials (Deerfield Beach, Fla.)

|October 6, 2015

Summary

Blue phase liquid crystals (BPs) form cubosomes that change optically with biological molecules. This study details BP droplet formation and how confinement and lipids affect their properties.

Keywords:

biological adsorbates blue phases liquid crystals microdroplets responsive cubosomes

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Area of Science:

Materials Science
Physical Chemistry
Nanotechnology

Background:

Cubosomes are self-assembled nanostructures with unique properties.
Blue phase liquid crystals (BPs) exhibit temperature-dependent structural transitions.
Optical responses of materials to biological molecules are crucial for sensing applications.

Purpose of the Study:

To investigate the formation of aqueous dispersions of blue phase liquid crystals (BPs).
To characterize the effects of confinement and lipids on BP droplet phase behavior.
To analyze the impact on optical appearance and morphology of BP droplets.

Main Methods:

Preparation of aqueous dispersions of BPs.
Microscopy techniques to observe droplet morphology.
Optical spectroscopy to analyze phase behavior and optical responses.

Main Results:

Successful formation of aqueous BP dispersions.
Demonstrated influence of confinement on BP phase behavior.
Observed changes in optical properties due to lipid interactions.
Characterized distinct droplet morphologies.

Conclusions:

Aqueous BP dispersions offer a platform for responsive materials.
Confinement and lipid interactions significantly modulate BP properties.
These findings are relevant for developing novel biosensors and drug delivery systems.