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Synthesis and characterization of a trans-1 hexakis-fullerene linker that forms crystalline polymers with silver
Chia-Hsiang Chen1, Amineh Aghabali, Alejandro J Metta-Magana
1Department of Chemistry, University of Texas at El Paso, El Paso, TX 79968, USA. echegoyen@utep.edu.
Abstract:
A new flexible hexakis-fullerene adduct with two bis(pyridin-4-ylmethyl)malonate groups located at trans-1 positions was synthesized. Via reaction with Ag(PF6) under two different conditions, two new 1D coordination polymers were obtained; under a nitrogen atmosphere, the silver ions are connected by argentophilic interactions but under an ambient atmosphere, the silver ions exhibit no interaction between them but coordination to the (H2PO4)(-) ions.
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