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Updated: Apr 1, 2026

An In Vitro Enzymatic Assay to Measure Transcription Inhibition by GalliumIII and H3 5,10,15-trispentafluorophenylcorroles

An In Vitro Enzymatic Assay to Measure Transcription Inhibition by GalliumIII and H3 5,10,15-trispentafluorophenylcorroles

Published on: March 18, 2015

5,10,15-Triferrocenylcorrole Complexes.

Giuseppe Pomarico¹, Pierluca Galloni¹, Federica Mandoj¹

¹Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata , via della Ricerca Scientifica 1, 00133 Rome, Italy.

Inorganic Chemistry

|October 14, 2015

Summary

Synthesizing ferrocenylcorrole complexes improved reaction yields. Unexpectedly, nickel insertion caused ring opening, yielding a linear tetrapyrrole nickel complex, while copper and cobalt complexes formed as expected.

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Published on: August 12, 2019

Area of Science:

Coordination Chemistry
Organometallic Chemistry
Macromolecular Chemistry

Background:

Corroles are macrocyclic compounds with potential applications in catalysis and materials science.
Ferrocenyl groups can be incorporated into macrocycles to tune electronic and redox properties.

Purpose of the Study:

To synthesize and characterize metal complexes of 5,10,15-triferrocenylcorrole.
To investigate the effect of ferrocenyl group substitution on corrole complex properties.
To explore the reactivity of ferrocenylcorroles during metal insertion.

Main Methods:

Synthesis of 5,10,15-triferrocenylcorrole and its metal complexes (Cu, Co, Ni).
Spectroscopic characterization (NMR, UV-Vis, etc.), electrochemistry, and spectroelectrochemistry.
Density functional theory (DFT) calculations.

Main Results:

Successful synthesis of copper and triphenylphosphinecobalt 5,10,15-triferrocenylcorrole complexes.
Unexpected ring opening of the macrocycle upon nickel insertion, yielding a linear tetrapyrrole nickel complex.
Synthesis of copper complexes with varying ferrocenyl group numbers (mono- and di-substituted) to study substituent effects.

Conclusions:

Direct complexation enhances corrole stability and reaction yield.
Nickel insertion into ferrocenylcorroles can lead to macrocycle fragmentation.
The number and position of ferrocenyl groups significantly influence the spectroscopic and electrochemical properties of the metal complexes.