Atomic and optical properties of warm dense copper

The emission of x rays from warm dense matter is of great interest for both spectroscopic diagnostics and development of intense x-ray sources. We report the results from the collisional-radiative steady-state (CRSS) modeling of atomic and optical properties of copper plasmas at near-solid and solid-state density for a range of temperatures. The CRSS model is validated against the available data on the average charge state and shifts of energy levels in aluminum and the opacity and emissivity spectra of carbon and aluminum plasmas. The average charge states, number density of ion species, and free electrons as a function of temperature are investigated for the solid-density copper plasma. Due to the dense plasma environment the four outer electrons are found to be unbounded even in the low-temperature limit ∼1eV. As the temperature changes from 1 to 100 eV, the predominant species vary from fivefold- to twelvefold-ionized copper ions. The opacity and emissivity spectra of dense copper plasmas are studied using the local thermodynamic equilibrium (LTE) and non-LTE approaches. It is found that the non-LTE effects are important in the spectral region of soft x rays emitted from the K shell. The emissivity in spectral lines is completely suppressed, indicating the importance of the energy-dissipating radiative processes in this soft x-ray region. Line broadening and redshifts of the K- and L-shell spectral lines toward higher wavelengths are observed with the increase of plasma density. These results have important implications for understanding the radiative properties of warm dense copper and can be useful for future experimental studies.