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Updated: Mar 1, 2026

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Published on: February 9, 2021
Synthesis and Thermal Behavior of a Fused, Tricyclic 1,2,3,4-Tetrazine Ring System
David E Chavez1, Jeffery C Bottaro2, Mark Petrie2
1M Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (USA). dechavez@lanl.gov.
Abstract:
This study presents the synthesis and characterization of a fused, tricyclic 1,2,3,4-tetrazine ring system. The molecule is synthesized in a three-step process from 5,5'-dinitro-bis,1,2,4-triazole via a di-N-amino compound. Oxidation to form the azo-coupled fused tricyclic 1,2,3,4-tetrazine is achieved using tert-butyl hypochlorite as the oxidant. The di-N-amino compound and the desired fused tricyclic 1,2,3,4-triazine display interesting thermal behavior and are predicted to be high-performance energetic materials.
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