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Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
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Published on: October 5, 2019

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Molecular co-catalyst accelerating hole transfer for enhanced photocatalytic H2 evolution

Wentuan Bi1, Xiaogang Li1, Lei Zhang1

  • 1Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, Synergetic Innovation Center of Quantum Information and Quantum Physics, Hefei Science Center of CAS, CAS Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China, Hefei 230026, Anhui, China.

Nature Communications
|October 22, 2015
PubMed
Summary

Water-soluble molecules like trifluoroacetic acid (TFA) accelerate hole transfer in artificial photocatalysis. This boosts hydrogen production efficiency by reducing charge recombination, offering a noble-metal-free alternative.

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