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Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
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Berry Phase Modification to the Energy Spectrum of Excitons
Jianhui Zhou1, Wen-Yu Shan1, Wang Yao2
1Department of Physics, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, USA.
Physical Review Letters
|November 10, 2015
Summary
Berry curvature causes energy splitting in excitons with opposite angular momentum. This effect, analogous to spin-orbit coupling, highlights Berry curvature
Area of Science:
- Condensed Matter Physics
- Materials Science
- Quantum Mechanics
Background:
- Excitons are fundamental quasiparticles in condensed matter systems, crucial for understanding optical and electronic properties.
- The hydrogenic model provides a basic framework for exciton behavior, but may not capture all quantum mechanical effects.
- Berry curvature is a geometric property of quantum systems that influences particle dynamics and topological phenomena.
Purpose of the Study:
- To investigate the role of Berry curvature in the semiclassical motion of excitons.
- To determine how Berry curvature influences energy splitting between exciton states.
- To explore the connection between Berry curvature effects and relativistic quantum mechanics in excitons.
Main Methods:
- Quantization of the semiclassical motion of excitons.
- Utilizing the gapped two-dimensional Dirac equation as a theoretical model.
- Analysis of Berry curvature flux through k-space.
Main Results:
- Berry curvature induces an energy splitting between exciton states with opposite angular momentum.
- This splitting is directly related to the Berry curvature flux over the exciton's relative motion k-space.
- The observed splitting can be interpreted as an effective spin-orbit coupling, with additional energy shifts from relativistic terms.
Conclusions:
- The study reveals limitations of the traditional hydrogenic model for describing excitons.
- Berry curvature plays a significant role in exciton behavior, particularly in the effective mass approximation.
- This work underscores the importance of geometric phase effects in condensed matter physics.
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