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Luminescent Polymer Composite Films Containing Coal-Derived Graphene Quantum Dots
Anton Kovalchuk1, Kewei Huang1, Changsheng Xiang1
1Department of Chemistry, ∥Department of Materials Science and NanoEngineering, and †Smalley Institute for Nanoscale Science and Technology, Rice University , 6100 Main Street, Houston, Texas 77005, United States.
ACS Applied Materials & Interfaces
|November 10, 2015
Summary
Coal-derived graphene quantum dots (GQDs) create fluorescent poly(vinyl alcohol) (PVA) composites. These luminescent polymer nanocomposites show potential for optoelectronic applications like LEDs and displays.
Area of Science:
- Materials Science
- Polymer Chemistry
- Nanotechnology
Background:
- Poly(vinyl alcohol) (PVA) is a versatile polymer matrix.
- Graphene quantum dots (GQDs) offer unique fluorescent properties.
- Developing novel luminescent materials is crucial for advanced optoelectronics.
Purpose of the Study:
- To prepare and characterize luminescent polymer composite films using PVA and coal-derived GQDs.
- To investigate the optical, thermal, and fluorescent properties of these nanocomposites.
- To evaluate their suitability for optoelectronic applications.
Main Methods:
- Fabrication of PVA/GQD nanocomposite films via solution casting from aqueous solutions.
- Characterization of optical properties, including transparency and photoluminescence.
- Assessment of thermal stability and nanoparticle dispersion within the polymer matrix.
Main Results:
- Composite films exhibited solid-state fluorescence due to coal-derived GQDs.
- High optical transparency (78-91%) and excellent nanoparticle dispersion were observed at 1-5 wt% GQD.
- Maximum photoluminescence intensity was achieved at 10 wt% GQD content.
Conclusions:
- PVA/GQD nanocomposites demonstrate promising luminescent properties.
- The materials possess good optical transparency and nanoparticle dispersion.
- These findings suggest potential applications in LEDs, flexible displays, and other optoelectronic devices.
Keywords:
fluorescent polymer compositesgraphene quantum dotslight emitting diodesluminescent polymer compositesnanocompositespoly(vinyl alcohol)
