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Deviation of polarity from linearity in liquid mixtures containing an ionic liquid
Vijay Beniwal1, Shashi K Shukla1, Anil Kumar1
1Physical & Materials Chemistry Division, CSIR-National Chemical Laboratory, Pune 411008, India. a.kumar@ncl.res.in.
Abstract:
The physico-chemical properties of liquid mixtures, in general, exhibit deviations from linear behaviour with respect to their composition, arising out of different types of cross-intermolecular interactions (both specific and non-specific). These specific and non-specific interactions can however be monitored to obtain the linear mixing in liquid mixtures using the pseudo-solvent methodology in such a manner that the interactions causing deviations from linearity are cancelled out and mixtures display linear behaviour.
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