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Insertion Homo- and Copolymerization of Diallyl Ether.

Zhongbao Jian1, Stefan Mecking2

  • 1Chair of Chemical Materials Science, Department of Chemistry, University of Konstanz, Universitätsstrasse 10, 78457 Konstanz (Germany).

Angewandte Chemie (International Ed. in English)
|November 14, 2015
PubMed
Summary

Palladium-catalyzed polymerization of diallyl ether overcomes previous limitations, enabling selective cyclic ether formation and high incorporation into ethylene polymers. This breakthrough allows for the synthesis of poly-diallyl ether with significant polymerization degrees.

Keywords:
allyl monomerhomogeneous catalysisinsertionpalladiumpolymerization

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