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Electroactive Polymer Nanoparticles Exhibiting Photothermal Properties
Published on: January 8, 2016
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Turning the heat on conjugated polyelectrolytes: an off-on ratiometric nanothermometer
Ghinwa H Darwish1, Ali Koubeissi1, Tharallah Shoker1
1The Department of Chemistry, American University of Beirut, P.O. Box 11-0236, Beirut, Lebanon. pierre.karam@mail.aub.edu.lb.
Abstract:
We report a self-referenced ratiometric nanothermometer based on short conjugated polyelectrolytes. An amphiphilic macromolecule destabilizes the polymer π-π stacking and makes it possible to shift the equilibrium between the less emissive aggregated state (520 nm) and the brighter individual chain (450 nm) within 20.0 °C and 70.0 °C.

