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Updated: Mar 29, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Crystal structure of 3-meth-oxy-2-[5-(naphthalen-1-yl)-4,5-di-hydro-1H-pyrazol-3-yl]phenol
1Department of Applied Chemistry, Dongduk Women's University, Seoul 136-714, Republic of Korea.
Abstract:
In the title compound, C20H18N2O2, the central pyrazoline ring has an envelope conformation with the atom substituted by the naphthalene ring as the flap. It bridges a benzene ring and a naphthalene ring system which are almost normal to one another, making a dihedral angle of 82.03 (6) °. There is an intra-molecular O-H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, mol-ecules are linked by pairs of N-H⋯π inter-actions, forming inversion dimers. There are also C-H⋯π inter-actions present and the dimers are linked via C-H⋯O hydrogen bonds, forming ribbons propagating along the a-axis direction.
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