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Soft nanotubes acting as confinement effecters and chirality inducers for achiral polythiophenes

Naohiro Kameta1, Mitsutoshi Masuda, Toshimi Shimizu

  • 1Research Institute for Sustainable Chemistry, Department of Materials and Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. n-kameta@aist.go.jp.

Chemical Communications (Cambridge, England)
|November 28, 2015
PubMed

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...