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Published on: February 18, 2014
Determination of the kinetic parameters of BeO using isothermal decay method
Juan Azorin Nieto1, Claudia Azorin Vega2, Teodoro Rivera Montalvo3
1Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340 México D.F., México.
Abstract:
Most of the existing methods for obtaining the frequency factors make use of the trap depth (activation energy) making some assumptions about the order of the kinetics. This causes inconsistencies in the reported values of trapping parameters due that the values of the activation energy obtained by different methods differ appreciably among them. Then, it is necessary to use a method independent of the trap depth making use of the isothermal luminescence decay (ILD) method. The trapping parameters associated with the prominent glow peak of BeO (280°C) are reported using ILD method. As a check, the trap parameters are also calculated by glow curve shape (Chen's) method after isolating the prominent glow peak by thermal cleaning technique. Our results show a very good agreement between the trapping parameters calculated by the two methods. ILD method was used for determining the trapping parameters of BeO. Results obtained applying this method are in good agreement with those obtained using other methods, except in the value of the frequency factor.
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