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Updated: Mar 28, 2026
Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
A Highly Energetic N-Rich Metal-Organic Framework as a New High-Energy-Density Material
Huabin Zhang1,2, Mingjian Zhang1, Ping Lin1
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences Fuzhou, Fujian, 350002, P. R. China.
Abstract:
Metal-organic framework (MOF)-based energetic material [Cu3 (MA)2 (N3 )3 ] (1; MA=melamine) was synthesized and structurally characterized (47.55 % N). The structural analysis revealed the existence of unusual multiwalled tubular channels and interweaving of single and double helical units in 1. The standard molar enthalpy of formation was found to be 1788.73 kJ mol(-1) , which is the highest value among previously reported MOF-based energetic materials. The calculated detonation properties showed that 1 can be used as a potential explosive. Sensitivity tests revealed that 1 is insensitive and thus can function as a high-energy-density material with a favorable level of safety.
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