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Atomic Emission Spectroscopy: Instrumentation01:22

Atomic Emission Spectroscopy: Instrumentation

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The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers.  Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.
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AES is a powerful analytical technique, especially effective when used with plasma sources, producing abundant spectra in characteristic emission lines. The Inductively Coupled Plasma (ICP), in particular, yields superior quantitative analytical data due to its high stability, low noise, low background, and minimal interferences under optimal experimental conditions. However, newer air-operated microwave sources are emerging as promising alternatives that could be more cost-effective than...
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German physicist Wilhelm Röntgen (1845–1923) was experimenting with electrical current when he discovered that a mysterious and invisible "ray" would pass through his flesh but leave an outline of his bones on a screen coated with a metal compound. In 1895, Röntgen made the first durable record of the internal parts of a living human: an "X-ray" image (as it came to be called) of his wife’s hand. Scientists worldwide quickly began their own experiments with...
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Related Experiment Videos

[Time-Resolved XEOL Experiment System on BL14W1 at SSRF].

Zhao-hong Zhang, Zheng Jiang, Song Xue

    Guang Pu Xue Yu Guang Pu Fen Xi = Guang Pu
    |December 18, 2015
    PubMed
    Summary

    A new time-resolved X-ray excited optical luminescence (TRXEOL) system was developed at SSRF for advanced materials analysis. This system achieves high time resolution, enabling deeper understanding of luminescence behaviors and electronic structures.

    Related Experiment Videos

    Area of Science:

    • Materials Science
    • Spectroscopy
    • Synchrotron Radiation

    Context:

    • The Shanghai Synchrotron Radiation Facility (SSRF) has developed a novel time-resolved X-ray excited optical luminescence (TRXEOL) experimental system.
    • This system integrates timing, spectrometer, and nuclear instrument modules for precise luminescence measurements.
    • It leverages synchrotron X-ray pulses and storage ring time structures for time-correlated single photon counting.

    Purpose:

    • To develop and implement a TRXEOL system for time-resolved optical luminescence studies at SSRF.
    • To achieve high timing resolution (picosecond scale) for detailed analysis of luminescence dynamics.
    • To enable combined optical and X-ray absorption fine structure spectroscopy (XAFS) for comprehensive material characterization.

    Summary:

    • The developed TRXEOL system utilizes a self-developed timing system with 6 ps jitter and 5 ps resolution.
    • Key components include Constant Fraction Discriminator, Time to Amplitude Converter, and Multi-Channel Analyzer for accurate data acquisition.
    • The system demonstrated a time resolution of less than 1 ns, successfully analyzing ZnO nanowire luminescence decay and spectra.

    Impact:

    • Enables in-depth investigation of luminescence behaviors and electronic structures through time-resolved optical and XAFS measurements.
    • Provides a feasible and reliable platform for time-resolved techniques at synchrotron facilities.
    • Advances the capabilities of the SSRF XAFS beamline for complex material analysis.