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Published on: October 31, 2019
Structural Transition of Cinnamate-Based Light-Responsive Ionic Liquids in Aqueous Solutions and Their Light-Tunable
Jie Yang1,2, Huiyong Wang1,3, Jianji Wang1,3
1Henan Key Laboratory of Green Chemical Media and Reactions, School of Chemistry and Chemical Engineering, Henan Normal University , Xinxiang, Henan 453007, P. R. China.
Abstract:
Light-responsive wormlike micelles have important applications in fields such as microfluids, photoswichable fluids, and rheology control. However, single-component light-responsive wormlike micelles formed only from a single tail surfactant have not been reported in literature. In this work, self-assembly behavior of 1-alkyl-3-methylimidazolium trans-ortho-methoxycinnamate [Cnmim][OMCA] (n = 8, 10, 12, 14, 16) ionic liquids in aqueous solutions is studied by UV-vis spectroscopy, viscosity, rheology, conductivity, and cryo-TEM measurements. It is found for the first time that, among the single tail ionic liquid surfactants studied, [C16mim][OMCA] can form wormlike micelles in aqueous solutions without any additives and light irradiation. Then these wormlike micelles are able to transform into cylindrical micelles under UV light irradiation, resulting in significantly tunable rheological properties of the solutions. The photoisomerization of anion of [C16mim][OMCA] from trans- to cis-isomer as well as the relative hydrophilicity and structural feature of the cis-isomer are suggested to be responsible for such transition.
