X-ray Fluorescence Imaging of Frozen Aqueous NaCl Solutions

In frozen aqueous NaCl, the liquid phase (LP) should coexist with ice at temperatures between the melting point and eutectic point of the system. The LP forms grooves on the surface of ice. In the present study, the morphology of the surface LP is examined by synchrotron radiation X-ray fluorescence (XRF). These measurements afford 2D distribution maps for Cl(-) as a major component, in addition to coexistent metal ions (Mn(2+), Co(2+), Cu(2+), and Zn(2+)). The 2D images obtained for Cl(-) indicate that a Y-shaped surface groove is formed in an observation area. Mn(2+) and Co(2+) are simply enriched in the LP together with Cl(-). In contrast, Cu(2+) and Zn(2+) exhibit behavior that is different from that of Mn(2+) and Co(2+), and they are concentrated at particular locations that are obviously off of the LP; this tendency is more apparent for Zn(2+). The 2D images are converted into 3D images by taking into consideration the freeze concentration in the LP and the attenuation of X-rays. The depth is largest in the middle of the groove, particularly at the intersection of surface grooves.