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Fabrication of Superhydrophobic Metal Surfaces for Anti-Icing Applications
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Durable Microstructured Surfaces: Combining Electrical Conductivity with Superoleophobicity.

Zihe Pan1,2, Tianchang Wang1,2, Shaofan Sun1,2,3

  • 1Department of Chemical Engineering, University of Waterloo , Waterloo, Ontario N2L3G1, Canada.

ACS Applied Materials & Interfaces
|December 30, 2015
PubMed
Summary
This summary is machine-generated.

This study developed conductive and superoleophobic polydimethylsiloxane (PDMS) by embedding silver flakes and nanowires. The material exhibits excellent stretchability and reversibility, suitable for advanced electronic devices.

Keywords:
durabilityelectrical conductivitymicrostructured surfacestretchable filmsuperoleophobicity

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Nanotechnology

Background:

  • Polydimethylsiloxane (PDMS) is an insulating elastomer.
  • Developing multifunctional elastomers with both electrical conductivity and superoleophobicity is challenging.
  • Existing methods often lack scalability or durability.

Purpose of the Study:

  • To fabricate electrically conductive and superoleophobic PDMS.
  • To investigate the effect of silver flakes (SFs) and silver nanowires (SNWs) on PDMS properties.
  • To create a versatile material for microstructured conductive devices.

Main Methods:

  • Embedding SFs and SNWs into microstructured FDTS-blended PDMS.
  • Characterizing electrical conductivity via percolation threshold and conductivity measurements.
  • Evaluating superoleophobicity through surface modification and microstructuring.
  • Testing mechanical properties like stretchability and reversible electrical response.

Main Results:

  • Achieved electrical conductivity at a percolation threshold of 3.0 × 10⁻² mg/mm² for SFs, reaching 1.12 × 10⁵ S/m.
  • Incorporating SNWs improved conductivity threefold compared to SFs alone due to enhanced conductive pathways.
  • The composite material demonstrated strong filler adhesion, retained properties under load (8.0 N), and exhibited high stretchability and reversible electrical behavior.
  • Superoleophobicity was successfully imparted via synergistic surface modification and microstructuring.

Conclusions:

  • A facile method for creating conductive and superoleophobic PDMS was demonstrated.
  • The developed material offers tunable electrical properties and robust mechanical performance.
  • This work provides a pathway for fabricating advanced microstructured devices with multifunctional properties.