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Solvent transport through hard-soft segmented polymer nanocomposites.

Sangram K Rath1, Saji S Edatholath2, T Umasankar Patro3

  • 1Naval Materials Research Laboratory, Shil-Badlapur Road, Ambernath, Maharashtra 421506, India.

Physical Chemistry Chemical Physics : PCCP
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Solvent transport in polyurethane nanocomposites showed non-monotonic diffusivity, defying traditional models. Nanoscale fillers alter polymer morphology, influencing solvent diffusion in complex ways.

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Area of Science:

  • Materials Science
  • Polymer Science
  • Nanotechnology

Background:

  • Understanding solvent transport in polymers is crucial for material design.
  • Polyurethane nanocomposites offer tunable properties but their transport behavior is complex.
  • Classical theories predict monotonic changes in diffusivity with filler content.

Purpose of the Study:

  • Investigate toluene transport in segmented polyurethane-clay nanocomposites.
  • Analyze the relationship between filler concentration and solvent diffusivity.
  • Elucidate the role of filler-induced morphological changes on solvent transport.

Main Methods:

  • Transport studies using toluene as a solvent.
  • Measurement of solvent diffusivity and equilibrium swelling.
  • Pre- and post-swollen segmented phase analysis of polymer nanocomposites.
  • Comparison of experimental data with classical tortuous path theory and free volume measurements.

Main Results:

  • Observed non-monotonic solvent diffusivity with increasing clay volume fraction.
  • Significant deviations between experimental and theoretically estimated diffusivity.
  • No change in equilibrium swelling (solubility coefficient) with filler content.
  • Identified filler-altered hard-soft segmented morphology influencing solvent interaction.

Conclusions:

  • Nanoscale fillers exert non-barrier influences on solvent diffusivity in phase-segmented block copolymers.
  • Filler concentration significantly affects the spatial distribution and reorientation of polymer segments upon solvent interaction.
  • Postulated a mechanism where filler-induced thermodynamic phase separation drives non-monotonic solvent transport behavior.