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Creating Patterned Conjugated Polymer Images Using Water-Compatible Reactive Inkjet Printing.

Seongho Jeon1, Sumin Park1, Jihye Nam2

  • 1Department of Chemical Engineering, Hanyang University , Seoul 133-791, Korea.

ACS Applied Materials & Interfaces
|January 6, 2016
PubMed
Summary

Researchers developed a reactive inkjet printing (RIJ) method to create poly(phenylenevinylene) (PPV) patterns on paper. This technique enables large-scale, inexpensive fabrication of functional polymer images using common inkjet printers.

Keywords:
PPVconjugated polymeroffice inkjet printerpaper substratereactive inkjet printing

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Organic Electronics

Background:

  • Conjugated polymer patterning is crucial for functional materials.
  • Inkjet printing offers scalable and cost-effective fabrication.
  • Existing methods are limited to water-compatible polymers like polyaniline (PANI) and poly(3,4-ethylenedioxythiophene) (PEDOT).

Purpose of the Study:

  • To develop a method for fabricating poly(phenylenevinylene) (PPV) patterns on paper using inkjet printing.
  • To demonstrate the versatility of the method for creating microarrayed patterns on various substrates.

Main Methods:

  • Reactive Inkjet Printing (RIJ) using a common office inkjet printer.
  • Printing of hydrophilic terephthaldehyde, bis(triphenylphosphonium salt), and potassium t-butoxide.
  • In situ Wittig reaction to form PPV patterns.
  • Utilizing a piezoelectric dispenser for microarrayed patterns on glass and PDMS.

Main Results:

  • Successful fabrication of PPV patterns on paper via RIJ.
  • Generation of microarrayed PPV patterns on glass and PDMS substrates.
  • The in situ prepared PPV is insoluble in water and chloroform, allowing for efficient byproduct removal.

Conclusions:

  • The RIJ method provides a facile and inexpensive route for patterning PPV on paper and other substrates.
  • This technique expands the range of printable conjugated polymers beyond water-compatible inks.
  • The insolubility of PPV facilitates purification, enhancing the quality of fabricated patterns.