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Updated: Mar 27, 2026

Thermochemical Studies of NiII and ZnII Ternary Complexes Using Ion Mobility-Mass Spectrometry
Published on: June 8, 2022
I2-induced SC-SC transformation within two-dimensional Zn(ii)-triazole framework: an ideal detector of
Ying Wang1, Jin-Min Yi2, Meng-Yuan Zhang2
1Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China. wangying790601@163.com and Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China.
Abstract:
A novel interpenetrated 2D + 2D → 2D architechture {[Zn(BTPS)(TPA)]·1.5DMF·H2O}n () has been constructed under solvothermal conditions. Interestingly, I2-induced single-crystal-to-single-crystal transformation to {[Zn(BTPS)(I)(TPA)1.5]·1.5H2O}n () showed a 2D + 1D → 2D array. Luminescent properties indicated that represents the first example of selective recognition toward cyano-containing molecules.

