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Updated: Mar 26, 2026

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Exciton dynamics in perturbed vibronic molecular aggregates
C Brüning1, J Wehner1, J Hausner1
1Universität Würzburg, Institut für Physikalische und Theoretische Chemie, Am Hubland , Campus Nord, Emil-Fischer-Str. 42, 97074 Würzburg, Germany.
Abstract:
A site specific perturbation of a photo-excited molecular aggregate can lead to a localization of excitonic energy. We investigate this localization dynamics for laser-prepared excited states. Changing the parameters of the electric field significantly influences the exciton localization which offers the possibility for a selective control of this process. This is demonstrated for aggregates possessing a single vibrational degree of freedom per monomer unit. It is shown that the effects identified for the molecular dimer can be generalized to larger aggregates with a high density of vibronic states.
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