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Induced Electric Dipoles01:28

Induced Electric Dipoles

5.0K
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
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Forced Oscillations01:06

Forced Oscillations

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When an oscillator is forced with a periodic driving force, the motion may seem chaotic. The motions of such oscillators are known as transients. After the transients die out, the oscillator reaches a steady state, where the motion is periodic, and the displacement is determined.
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Van der Waals Interactions01:24

Van der Waals Interactions

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Atoms and molecules interact with each other through intermolecular forces. These electrostatic forces arise from attractive or repulsive interactions between particles with permanent, partial, or temporary charges. The intermolecular forces between neutral atoms and molecules are ion–dipole, dipole–dipole, and dispersion forces, collectively known as van der Waals forces.
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Design Example: Underdamped Parallel RLC Circuit01:17

Design Example: Underdamped Parallel RLC Circuit

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Consider designing an oscillator circuit, a crucial component in various electronic devices and systems. The objective is to create an oscillator circuit with specific characteristics: a damped natural frequency of 4 kHz and a damping factor of 4 radians per second. To accomplish this, a parallel RLC circuit is employed, known for its ability to sustain oscillations at a resonant frequency. In this case, the damping factor is pivotal in achieving the desired performance.
Starting with a fixed...
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Oscillations In An LC Circuit01:30

Oscillations In An LC Circuit

3.3K
An idealized LC circuit of zero resistance can oscillate without any source of emf by shifting the energy stored in the circuit between the electric and magnetic fields. In such an LC circuit, if the capacitor contains a charge q before the switch is closed, then all the energy of the circuit is initially stored in the electric field of the capacitor. This energy is given by
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Damped Oscillations01:07

Damped Oscillations

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In the real world, oscillations seldom follow true simple harmonic motion. A system that continues its motion indefinitely without losing its amplitude is termed undamped. However, friction of some sort usually dampens the motion, so it fades away or needs more force to continue. For example, a guitar string stops oscillating a few seconds after being plucked. Similarly, one must continually push a swing to keep a child swinging on a playground.
Although friction and other non-conservative...
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Related Experiment Video

Updated: Mar 26, 2026

Multiplex Chemical Imaging Based on Broadband Stimulated Raman Scattering Microscopy
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Multiplex Chemical Imaging Based on Broadband Stimulated Raman Scattering Microscopy

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Dispersion dipoles for coupled Drude oscillators.

Tuguldur T Odbadrakh1, Kenneth D Jordan1

  • 1Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA.

The Journal of Chemical Physics
|January 24, 2016
PubMed
Summary

We calculated dispersion-induced dipole moments for coupled Drude oscillators using two methods. The results show an R(-7) dependence, linking to C6/R(6) dispersion energy via the Hellmann-Feynman theorem.

Area of Science:

  • Quantum Chemistry
  • Atomic and Molecular Physics
  • Computational Chemistry

Background:

  • Dispersion forces, like van der Waals interactions, arise from fluctuating induced dipoles.
  • Understanding these interactions is crucial for molecular behavior and material properties.
  • Drude oscillator models are widely used to describe electronic response in materials.

Purpose of the Study:

  • To calculate dispersion-induced dipole moments for coupled Drude oscillators.
  • To investigate the dependence of these dipole moments on inter-oscillator separation.
  • To establish a connection between induced dipoles and dispersion energy.

Main Methods:

  • Second-order Rayleigh-Schrödinger perturbation theory to evaluate wave functions and dipole moments.

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  • Response theory involving integration over imaginary frequencies of polarizability and hyperpolarizability.
  • Analysis of dipole-dipole and dipole-quadrupole coupling effects.
  • Main Results:

    • Two distinct theoretical approaches yielded consistent results for dispersion-induced dipole moments.
    • The induced dipoles exhibit a characteristic R(-7) dependence on the separation (R) between oscillators.
    • A direct link was established between these dipoles and the C6/R(6) dispersion energy term.

    Conclusions:

    • The study provides a robust theoretical framework for calculating dispersion-induced dipoles.
    • The R(-7) dependence is a key signature of these interactions.
    • The Hellmann-Feynman theorem elegantly connects induced dipoles to macroscopic dispersion energy.