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Strongly Enhanced Water Splitting Performance of Ta3 N5 Nanotube Photoanodes with Subnitrides
Lei Wang1, Xuemei Zhou1, Nhat Truong Nguyen1
1Department of Materials Science and Engineering, WW4-LKO, University of Erlangen-Nuremburg, Martensstrasse 7, D-91058, Erlangen, Germany.
Abstract:
Subnitrides strongly enhance the efficiency of Ta3 N5 -nanotube photoanodes in photochemical water splitting. The fabrication of Ta3 N5 nanotube layers with a controlled subnitride layer at the interface to the back contact is demonstrated. The insertion of this subnitride layer has a strong influence on the electron transfer to the back contact, and as a result leads to a drastic shift in photocurrent onset potential and a considerable enhancement of photocurrent conversion efficiency.

