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Superconductor01:24

Superconductor

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A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
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Types Of Superconductors01:28

Types Of Superconductors

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A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
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Theory of Metallic Conduction01:17

Theory of Metallic Conduction

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The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
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Diamagnetism01:26

Diamagnetism

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Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
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Semiconductors01:22

Semiconductors

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There is variation in the electrical conductivity of materials - metals, semiconductors, and insulators that are showcased with the help of the energy band diagrams.
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
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Ferromagnetism01:31

Ferromagnetism

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Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
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Updated: Mar 26, 2026

Seedless Growth of Bismuth Nanowire Array via Vacuum Thermal Evaporation
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Superconductivity in Bismuth. A New Look at an Old Problem.

Zaahel Mata-Pinzón1, Ariel A Valladares1, Renela M Valladares2

  • 1Departamento de Materia Condensada y Criogenia, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, México, D.F., México.

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Summary

Amorphous bismuth exhibits enhanced superconductivity due to increased electron-phonon coupling and electronic density of states at the Fermi energy compared to crystalline bismuth. This study explores atomic topology

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Superconductivity

Background:

  • Superconductivity in bismuth is influenced by its atomic structure.
  • Understanding the interplay between electronic, vibrational, and topological properties is crucial for predicting superconductivity.

Purpose of the Study:

  • To investigate the relationship between atomic topology, vibrational and electronic properties, and superconductivity in amorphous bismuth.
  • To compare the properties of amorphous bismuth (a-Bi) with crystalline bismuth (x-Bi).

Main Methods:

  • Computer generation of a 216-atom amorphous bismuth structure (a-Bi216) using an undermelt-quench approach.
  • Calculation of pair distribution function, electronic density of states (eDOS), and vibrational density of states (vDOS).
  • Estimation of superconducting transition temperature using BCS theory and McMillan's formula to determine electron-phonon coupling (λ).

Main Results:

  • The pair distribution function of a-Bi216 closely matches experimental data.
  • Amorphous bismuth shows approximately 4 times higher electronic density of states at the Fermi energy compared to crystalline bismuth.
  • While the energy range of vDOS is similar, its shape differs significantly between amorphous and crystalline bismuth.
  • Electron-phonon coupling (λ) is substantially higher in amorphous bismuth (λa = 2.46) than in crystalline bismuth (λc = 0.24).

Conclusions:

  • Superconductivity in amorphous bismuth is enhanced compared to crystalline bismuth.
  • The enhancement is attributed to higher electron-phonon coupling (λ) and increased electronic density of states at the Fermi energy in the amorphous structure.