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Updated: Mar 26, 2026

Quantitative 31P NMR Analysis of Lignins and Tannins
Published on: August 2, 2021
Condensed tannins in extracts from European medicinal plants and herbal products
Honorata M Ropiak1, Aina Ramsay1, Irene Mueller-Harvey1
1Chemistry and Biochemistry Laboratory, School of Agriculture, Policy and Development, University of Reading, P O Box 236, Reading RG6 6AT, UK.
Abstract:
Medicinal plant materials are not usually analysed for condensed tannins (CT). Thirty commercially available European medicinal plants and herbal products were screened for CT and fourteen CT samples were analysed in detail. This is also the first comprehensive CT analysis of pine buds, walnut leaves, heather flowers and great water dock roots. Acetone/water extracts contained between 3.2 and 25.9 g CT/100g of extract, had CT with mean degrees of polymerisation of 2.9 to 13.3, procyanidin/prodelphinidin ratios of 1.6/98.4 to 100/0 and cis/trans flavan-3-ol ratios of 17.7/82.3 to 97.3/2.7. The majority of samples contained procyanidins, four contained A-type linkages (blackthorn flowers, heather flowers, bilberry leaves and cowberry leaves) and one sample also had galloylated procyanidins (great water dock roots).

