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Updated: Mar 26, 2026

Chemiluminescence-based Assays for Detection of Nitric Oxide and its Derivatives from Autoxidation and Nitrosated Compounds
Published on: February 16, 2022
Product Channels in the Reaction of the Hydroxymethyl Radical with Nitric Oxide
Wenhui Feng1, Erik Janssen1, John F Hershberger1
1Department of Chemistry and Biochemistry, Dept. 2735, PO Box 6050, North Dakota State University , Fargo, North Dakota 58108-6050, United States.
Abstract:
The products of the reaction of CH2OH with NO were studied by infrared diode laser spectroscopy. Products were detected to determine the branching ratios of the CH2OH + NO reaction. HNCO was detected in 10.3 ± 2% yields. No other products were detected in significant quantities, indicating that adduct formation is the primary reaction pathway. Ab initio calculations of the potential energy surface show a low energy pathway to HNCO + H2O, but no other bimolecular channels, in agreement with the experiments.
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