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Updated: Mar 26, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Gold(I)-Catalyzed Allenyl Cope Rearrangement: Evolution from Asynchronicity to Trappable Intermediates Assisted by

Dinesh V Vidhani1, Marie E Krafft1, Igor V Alabugin1

  • 1Department of Chemistry & Biochemistry, Florida State University , Tallahassee, Florida 32306, United States.

Journal of the American Chemical Society
|February 7, 2016
PubMed
Summary

This study introduces novel strategies using gold(I) catalysis to interrupt concerted pericyclic reactions, enabling new cascade transformations. By controlling electronic and stereoelectronic factors, chemists can now access interrupted Cope rearrangements.

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