Recent advances in graphene-based nanomaterials for fabricating electrochemical hydrogen peroxide sensors

Due to the large specific surface area, extraordinary mechanical flexibility, chemical stability, and superior electrical and thermal conductivities, graphene (G)-based materials have recently opened up an exciting field in the science and technology of two-dimensional (2D) nanomaterials with continuously growing academic and technological impetus. In the past several years, graphene-based materials have been well designed, synthesized, and investigated for sensing applications. In this review, we discuss the synthesis and application of graphene-based 2D nanomaterials for the fabrication of hydrogen peroxide (H₂O₂) electrochemical sensors. In particular, graphene-based nanomaterials as immobilization matrix of heme proteins for the fabrication of enzymatic H₂O₂ electrochemical biosensors is first summarized. Then, the application of graphene-based electrocatalysts (metal-free, noble-metals and non-noble metals) in constructing non-enzymatic H₂O₂ electrochemical sensors is discussed in detail. We hope that this review is helpful to push forward the advancement of this academic issue (189 references).