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Cubic Polyhedral Oligomeric Silsesquioxane Based Functional Materials: Synthesis, Assembly, and Applications.

Qun Ye1, Hui Zhou1, Jianwei Xu2

  • 1Institute of Materials Research and Engineering, Agency for Science, Research and Engineering (A*STAR), 2 Fusionopolis Way, Innovis, #08-03, Singapore, 138634, Singapore.

Chemistry, an Asian Journal
|February 17, 2016
PubMed
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Polyhedral oligomeric silsesquioxanes (POSS) enable novel hybrid materials. This review covers POSS chemistry, properties, and applications in polymers and advanced materials.

Keywords:
POSShybrid materialspolymersself-assemblysynthesis

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Nanotechnology

Background:

  • Organically modified cubic polyhedral oligomeric silsesquioxanes (POSS) are versatile nanoscale building blocks.
  • POSS moieties can be functionalized to create hybrid materials with tailored properties.
  • Incorporation into polymers yields functional polymeric materials with tunable characteristics.

Purpose of the Study:

  • To review recent advancements in the chemistry and applications of POSS-based molecules and polymers.
  • To discuss the properties and assembly behavior of POSS-based functional hybrid materials.
  • To explore the structure-property relationships in POSS-based hybrid materials.

Main Methods:

  • Literature review of recent developments in POSS chemistry and applications.
  • Analysis of properties and assembly behaviors of POSS-based hybrid materials.
  • Investigation of the intrinsic nature of the POSS unit and its influence on material performance.

Main Results:

  • POSS enables the design of functional hybrid materials for diverse applications.
  • Functionalization of POSS allows for precise control over material properties.
  • POSS-based polymers exhibit tunable physical properties for specific applications.

Conclusions:

  • POSS-based hybrid materials offer significant potential in various technological fields.
  • Understanding POSS chemistry and assembly is crucial for developing high-performance materials.
  • Further research into POSS-based materials will drive innovation in nanotechnology and polymer science.