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Published on: June 9, 2023
Thermal Magnetic Hysteresis in a Copper-Gadolinium-Radical Chain Compound
Mei Zhu1, Cun Li1, Xiufeng Wang1
1Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry and Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, Nankai University , Tianjin 300071, China.
Abstract:
Magnetic bistability spanning over a temperature domain of 40 K can result from a small structural deformation of the gadolinium aminoxyl coordination. This is illustrated for a nitronyl nitroxide 3d-4f chain, [Ln(hfac)3Cu(hfac)2(NIT-Pyrim)2] (Ln(III) = Gd, Dy), which is the first example of a bistable lanthanide-based complex.
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