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Self-assembly of a redox active water soluble Pd6L8 'molecular dice'
Bijan Roy1, Ennio Zangrando2, Partha Sarathi Mukherjee1
1Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore, India. psm@ipc.iisc.ernet.in.
Chemical Communications (Cambridge, England)
|March 3, 2016
Abstract:
A water soluble 'molecular dice' was synthesised via coordination driven self-assembly of a Pd(II) ion with a flexible cationic tritopic donor and was fully characterised using NMR, ESI-MS and single crystal X-ray diffraction analysis. The donor-inherited redox active nature of the 'molecular dice' was studied using cyclic voltammetry.
