Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Anionic Chain-Growth Polymerization: Overview01:20

Anionic Chain-Growth Polymerization: Overview

2.8K
The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
2.8K
Cationic Chain-Growth Polymerization: Mechanism00:57

Cationic Chain-Growth Polymerization: Mechanism

3.0K
The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the...
3.0K
Anionic Chain-Growth Polymerization: Mechanism01:04

Anionic Chain-Growth Polymerization: Mechanism

2.6K
The mechanism for anionic chain-growth polymerization involves initiation, propagation, and termination steps. In the initiation step, a nucleophilic anion, such as butyl lithium, initiates the polymerization process by attacking the π bond of the vinylic monomer. As a result, a carbanion, stabilized by the electron‐withdrawing group, is generated. The resulting carbanion acts as a Michael donor in the propagation step and attacks the second vinylic monomer, which acts as a Michael...
2.6K
Olefin Metathesis Polymerization: Overview01:13

Olefin Metathesis Polymerization: Overview

2.7K
Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
2.7K
Ziegler–Natta Chain-Growth Polymerization: Overview01:17

Ziegler–Natta Chain-Growth Polymerization: Overview

4.2K
Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta...
4.2K
Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)

2.3K
Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
2.3K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Polymer Nanoparticles as Functional Fillers for Composite Electrolytes for Batteries.

Industrial & engineering chemistry research·2026
Same author

Body surface potential mapping of the cortico-muscular axis using smart textile electrode arrays.

Nature communications·2026
Same author

Stepwise enzymatic synthesis of stereoregular poly(hydroxyalkanoates) starting from prochiral β-Keto esters.

Bioresource technology·2026
Same author

Unique Hierarchical Mesostructures Arising from Biobased Double-Crystalline PLLA-<i>b</i>-PHDO-<i>b</i>-PLLA ABA Triblock Copolymers.

Biomacromolecules·2026
Same author

Markers in umbilical cord blood in early-onset fetal growth restricted fetuses.

Placenta·2026
Same author

Polyampholyte Copolymers Based on Dual Ionic Monomers as Self-Healing Aqueous Binders for Lithium Ion Battery Cathodes.

ChemSusChem·2026

Related Experiment Video

Updated: Mar 24, 2026

Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by &#960;-&#960; Stacking Interactions
10:53

Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions

Published on: October 10, 2016

14.7K

Innovative Poly(Ionic Liquid)s by the Polymerization of Deep Eutectic Monomers.

Mehmet Isik1, Fernando Ruiperez1, Haritz Sardon1

  • 1POLYMAT, University of the Basque Country UPV/EHU, Avda. Tolosa 72, 20018, San Sebastian, Spain.

Macromolecular Rapid Communications
|March 9, 2016
PubMed
Summary

Researchers developed new, inexpensive poly(ionic liquid)s (PILs) using deep eutectic monomers (DEMs) derived from renewable resources. This facile synthesis offers a cost-effective alternative to traditional PILs for various applications, including CO2 capture.

Keywords:
CO2 capturedeep eutectic solventphotopolymerizationpoly(ionic liquid)s

More Related Videos

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

22.4K
From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

69.8K

Related Experiment Videos

Last Updated: Mar 24, 2026

Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by &#960;-&#960; Stacking Interactions
10:53

Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions

Published on: October 10, 2016

14.7K
Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

22.4K
From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding

Published on: March 24, 2018

69.8K

Area of Science:

  • Polymer Chemistry
  • Materials Science
  • Green Chemistry

Background:

  • Traditional poly(ionic liquid)s (PILs) offer advanced properties but are limited by high costs associated with fluorinated anions and complex synthesis.
  • There is a need for cost-effective, sustainable, and easily synthesized alternatives to current PILs for broader technological adoption.

Purpose of the Study:

  • To introduce a novel family of poly(ionic liquid)s (PILs) synthesized from inexpensive and renewable starting materials.
  • To demonstrate a facile synthetic route to these new PILs using deep eutectic monomers (DEMs).
  • To explore the potential applications of these novel PILs, such as in carbon dioxide (CO2) capture.

Main Methods:

  • Deep eutectic monomers (DEMs) were synthesized by mixing quaternary ammonium compounds with hydrogen bond donors (e.g., citric acid, terephthalic acid, amidoxime).
  • DEM formation was confirmed using differential scanning calorimetry (DSC), nuclear magnetic resonance (NMR), and computational studies.
  • DEMs were polymerized via mild photopolymerization or polycondensation strategies, with polymer formation verified through spectroscopic characterization.

Main Results:

  • A new class of deep eutectic monomers (DEMs) was successfully prepared from readily available, inexpensive chemicals.
  • The DEMs were shown to be liquid, facilitating their polymerization into poly(ionic liquid)s (PILs) using accessible methods.
  • The synthesized PILs demonstrated promising performance as solid sorbents for carbon dioxide (CO2) capture.

Conclusions:

  • The deep eutectic monomer route provides a viable, cost-effective, and environmentally friendly method for synthesizing novel poly(ionic liquid)s.
  • These new PILs are non-toxic, cheap, and easy to prepare, offering a significant advantage over existing PILs.
  • The developed PILs show potential for various applications, notably in CO2 capture technologies.