Degradation of the insecticide propoxur by electrochemical advanced oxidation processes using a boron-doped...

A solution with 0.38 mM of the pesticide propoxur (PX) at pH 3.0 has been comparatively treated by electrochemical oxidation with electrogenerated H₂O₂ (EO-H₂O₂), electro-Fenton (EF), and photoelectro-Fenton (PEF). The trials were carried out with a 100-mL boron-doped diamond (BDD)/air-diffusion cell. The EO-H₂O₂ process had the lowest oxidation ability due to the slow reaction of intermediates with ^•OH produced from water discharge at the BDD anode. The EF treatment yielded quicker mineralization due to the additional ^•OH formed between added Fe²⁺ and electrogenerated H₂O₂. The PEF process was the most powerful since it led to total mineralization by the combined oxidative action of hydroxyl radicals and UVA irradiation. The PX decay agreed with a pseudo-first-order kinetics in EO-H₂O₂, whereas in EF and PEF, it obeyed a much faster pseudo-first-order kinetics followed by a much slower one, which are related to the oxidation of its Fe(II) and Fe(III) complexes, respectively. EO-H₂O₂ showed similar oxidation ability within the pH range 3.0-9.0. The effect of current density and Fe²⁺ and substrate contents on the performance of the EF process was examined. Two primary aromatic products were identified by LC-MS during PX degradation.