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Updated: Mar 23, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
Crystal structure of
M A A A A Islam1, M C Sheikh2, M H Islam1
1Department of Chemistry, Rajshahi University of Engineering & Technology, Rajshahi 6204, Bangladesh.
Abstract:
The title compound, C32H30N4O2S4, consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hy-droxy-phenyl-ethyl-idene)di-thio-carbazate groups, which are connected through an S-S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88 (4)° between the S2C=N planes. A bifurcated intra-molecular O-H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, mol-ecules are linked by pairs of C-H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C-H⋯π inter-actions.
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