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Updated: Mar 23, 2026

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
A PYP chromophore acts as a 'photoacid' in an isolated hydrogen bonded complex
Lars H Andersen1, Anastasia V Bochenkova, Jørgen Houmøller
1Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C, Denmark. lha@phys.au.dk.
Abstract:
The light-induced response of a neutral Photoactive Yellow Protein chromophore in a hydrogen-bonded complex with a proton acceptor has been studied by dual-detection action absorption spectroscopy and density functional theory. We show that the chromophore is a 'photoacid' and that ultrafast excited-state proton transfer might be operative in an isolated complex.
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