Water-Stable Anionic Metal-Organic Framework for Highly Selective Separation of Methane from Natural Gas and
Lan Li1,2, Xusheng Wang2, Jun Liang2
1Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.
Abstract:
A 3D water-stable anionic metal-organic framework [Zn4(hpdia)2]·[NH2(CH3)2]·3DMF·4H2O (FJI-C4) was constructed based on an elaborate phosphorus-containing ligand 5,5'-(hydroxyphosphoryl)diisophthalic acid (H5hpdia). FJI-C4 with narrow one-dimensional (1D) pore channels exhibits high selectivity of C3H8/CH4 and C2H2/CH4. It is the first time for the MOF which contains phosphorus for selective separation of methane from natural gas and pyrolysis gas.
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