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Synthesis of Substrate-Bound Au Nanowires Via an Active Surface Growth Mechanism
Published on: July 18, 2018
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Molecular Gold Wire from Mixed-Valent Au(I/III) Complexes
1Institute of Inorganic and Applied Chemistry, Hamburg University, Martin-Luther-King-Platz 6, 20146, Hamburg, Gemany. matthiasboege@gmail.com.
Chemistry (Weinheim an Der Bergstrasse, Germany)
|April 1, 2016
Summary
Researchers synthesized novel mixed-valent gold complexes, revealing unique gold(I)-gold(III) interactions. These findings advance understanding of aurophilic bonding in gold chemistry.
Area of Science:
- Inorganic Chemistry
- Crystallography
- Materials Science
Background:
- Mixed-valent gold complexes are of interest due to their unique electronic and structural properties.
- Understanding gold-gold interactions is crucial for designing new materials and catalysts.
Purpose of the Study:
- To synthesize and characterize novel mixed-valent gold(I)/gold(III) complexes.
- To investigate the crystal structure and bonding in these new compounds.
Main Methods:
- Crystal growth from solutions of cyclohexanecarbonitrile and gold chlorides.
- X-ray crystallography for structural determination.
- Characterization of the synthesized compound.
Main Results:
- Successful synthesis of bis(cyclohexanecarbonitrile)gold(I) tetrachloridoaurate(III).
- Crystal structure reveals columnar arrangement of gold(I) and gold(III) atoms.
- Observed shortest unsupported gold(I)-gold(III) interactions at 324-325 pm.
Conclusions:
- The new structure exhibits significant aurophilic bonding between gold(I) and gold(III) centers.
- This study provides insights into short gold-gold distances and their implications.
- The findings contribute to the understanding of bonding in mixed-valent gold systems.
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