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Molecular Plasmonics.

Andrew J Wilson1, Katherine A Willets1

  • 1Department of Chemistry, Temple University, Philadelphia, Pennsylvania 19122;

Annual Review of Analytical Chemistry (Palo Alto, Calif.)
|April 7, 2016
PubMed
Summary
This summary is machine-generated.

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Molecular plasmonics explores the intricate interplay between plasmon resonances and molecules. Recent advances reveal molecules

Area of Science:

  • Physics and Chemistry
  • Nanotechnology
  • Materials Science

Background:

  • Molecular plasmonics traditionally focuses on sensing applications.
  • It involves complex interactions between plasmon resonances and molecules.
  • Molecules can intrinsically support plasmonic properties.

Purpose of the Study:

  • To review recent advances in molecular plasmonics beyond sensing.
  • To highlight the role of molecules in coupled molecule-plasmon systems.
  • To showcase the diverse applications of molecular plasmonics.

Main Methods:

  • Discussion of spectroscopic changes from molecular-plasmonic resonance interactions.
  • Analysis of tuning molecular properties for active plasmonic systems.
  • Experimental and theoretical examination of molecular adsorbate effects on surface-enhanced Raman scattering (SERS).
Keywords:
SERSactive plasmonicsplasmon-molecule couplingpolycyclic aromatic hydrocarbonssurface plasmon resonance

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  • Introduction to research utilizing molecules as plasmonic materials.
  • Main Results:

    • Spectroscopic shifts indicate strong coupling between molecular and plasmonic resonances.
    • Tailoring molecular properties enables the creation of active plasmonic devices.
    • Molecular position and polarizability significantly influence SERS signals.
    • Molecules can function as active plasmonic components.

    Conclusions:

    • Molecules are integral to coupled molecule-plasmon systems.
    • Molecular plasmonics offers diverse applications beyond traditional sensing.
    • Future research can leverage molecules for novel plasmonic functionalities.