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Ti(0) nanoparticles via lithium-naphthalenide-driven reduction

Christian Schöttle1, Dmitry E Doronkin, Radian Popescu

  • 1Institut für Anorganische Chemie, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, 76131 Karlsruhe, Germany. claus.feldmann@kit.edu.

Chemical Communications (Cambridge, England)
|April 19, 2016
PubMed

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Nitriles are reduced to amines in the presence of strong reducing agents like lithium aluminum hydride through a typical nucleophilic acyl substitution. The reaction requires two equivalents of the reducing agent. The reducing agent acts as a source of hydride ions.
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