Excimer-induced high-efficiency fluorescence due to pairwise anthracene stacking in a crystal with long lifetime
Haichao Liu1, Liang Yao1, Bao Li1
1State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun, 130012, P. R. China. yangbing@jlu.edu.cn.
Chemical Communications (Cambridge, England)
|April 26, 2016
Abstract:
Herein, we report an anthracene-based material, 2-(anthracen-9-yl)thianthrene (), whose crystal exhibits excimer fluorescence with an unexpected high luminous efficiency (up to 80%) and long lifetime (163.75 ns), due to pairwise anthracene stacking. These results will update the traditional view that excimers are poorly efficient in photoluminescence.
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