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Cellulosic fabrics printing with multifunctional encapsulated phthalocyanine pigment blue using phase separation
Ahmed A Haroun1, H A Diab2, O A Hakeim3
1Chemical Industries Research Division, National Research Center, Dokki, Cairo, Egypt.
Encapsulating C.I. Pigment Blue 15:3 within citric-acrylate (CAC) oligomers improves pigment printing on cellulosic fabrics. This innovation enhances antibacterial properties and fastness while reducing binder requirements.
Area of Science:
- Materials Science
- Textile Chemistry
- Polymer Science
Background:
- Traditional pigment printing on cellulosic fabrics faces challenges with efficiency and performance.
- Developing advanced encapsulation methods is crucial for improving pigment application and fabric properties.
Purpose of the Study:
- To formulate aqueous dispersions of citric-acrylate (CAC) oligomer encapsulating C.I. Pigment Blue 15:3 (PB15:3).
- To evaluate the impact of encapsulated PB15:3 on pigment printing efficiency, fabric properties, and antibacterial performance.
Main Methods:
- Phase separation method for CAC oligomer encapsulation of PB15:3.
- FT-IR spectroscopy and centrifuge sedimentation for confirming encapsulation.
- Thermal gravimetric analysis (TGA) and transmission electron microscopy (TEM) for characterization.
Main Results:
- Encapsulated pigment demonstrated multifunctional benefits, minimizing printing forces and accelerating fixation.
- Reduced binder requirements and improved one-step fixation without drying were observed.
- Printed fabrics exhibited enhanced antibacterial activity against E. coli and S. aureus.
- Superior light and washing fastness compared to control samples.
Conclusions:
- Citric-acrylate oligomer encapsulation offers a promising approach for advanced pigment printing on cellulosic textiles.
- The method enhances functional properties, including antibacterial activity and durability.
- This technique contributes to more efficient and effective textile coloration processes.
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