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Light-stimulated carrier dynamics of CuInS2/CdS heterotetrapod nanocrystals
Masanori Sakamoto1, Koki Inoue, Makoto Okano
1Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan. sakamoto@scl.kyoto-u.ac.jp teranisi@scl.kyoto-u.ac.jp.
Nanoscale
|April 28, 2016
Abstract:
We synthesized a heterotetrapod composed of a chalcopyrite(ch)-CuInS2 core and wurtzite(w)-CdS arms and elucidated its optical properties and light-stimulated carrier dynamics using fs-laser flash photolysis. The CuInS2/CdS heterotetrapod possessed quasi-type II band alignment, which caused much longer-lived charge separation than that in the isolated CuInS2 nanocrystal.

