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Formation of β Polymorphs in Milk Fats with Large Differences in Triacylglycerol Profiles
Daylan A Tzompa-Sosa1, Pere R Ramel1, Hein J F van Valenberg1
1Dairy Science and Technology Group, Food Quality and Design, Wageningen University , Wageningen, The Netherlands.
Abstract:
In this study, we characterized the polymorphism of milk fat (MF) with various TAG compositions during isothermal crystallization at 20 °C. TAG composition of MF from seven individual cows was determined using GC-FID and MALDI-TOF MS, and MF polymorphism was studied using X-ray diffraction. Results showed that TAG profile determines the polymorphic behavior of MF. Saturated TAG with carbon numbers 34-38 promoted the formation of α polymorphs, whereas unsaturated TAG with 52-54 promoted the formation of the β polymorphs. Furthermore, MFs with unsaturated fatty acid profiles were increased in unsaturated TAG with 52-54 carbons. The presence of MF crystals in the β polymorph has been controversial over the years as most authors mainly find MF crystals in the α and β' form. In our work, we showed that the β polymorph is formed in MF on the basis of its TAG composition.
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